Samarium(III) bromide

Samarium(III) bromide
Names
	IUPAC name samarium(III) bromide
	Other names samarium tribromide; tribromosamarium
Identifiers
CAS Number	13759-87-0;
3D model (JSmol)	Interactive image; Interactive image;
ChemSpider	75528;
ECHA InfoCard	100.033.938
EC Number	237-347-4;
PubChem CID	24868613;
CompTox Dashboard (EPA)	DTXSID4065608 ;
	InChI InChI=1S/3BrH.6H2O.Sm/h31H;61H2;/q;;;;;;;;;+3/p-3 Key: LXJDCZVUWJNXRL-UHFFFAOYSA-K;
	SMILES Br[Sm](Br)Br; [Br-].[Br-].[Br-].[Sm+3];
Properties
Chemical formula	SmBr3
Molar mass	390.07 g·mol−1
Appearance	Light yellow solid[1][2]
Melting point	700 °C (1,292 °F; 973 K)<[3]
Magnetic susceptibility (χ)	+972.0·10−6 cm3/mol
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335[3]
Precautionary statements	P261, P305+P351+P338[3]
Related compounds
Other anions	Samarium(III) fluoride; Samarium(III) chloride
Other cations	Samarium(II) bromide
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Samarium(III) bromide is a crystalline compound of one samarium and three bromine atoms with the chemical formula of SmBr₃. Samarium(III) bromide is a dark brown powder at room temperature.[4] The compound has a crystal structure isotypic to that of plutonium(III) bromide.[5][6]

Preparation

SmBr₃·6H₂O can be crystallized by dissolving samarium oxide in 40% hydrobromic acid. The hydrate and ammonium bromide are heated in a vacuum to obtain the anhydrous form of samarium(III) bromide.[2]

Other compounds

Samarium(III) bromide forms some compounds with hydrazine, such as SmBr₃·3N₂H₄·H₂O which is a pale yellow needle-shaped crystal that is soluble in water and ethanol but insoluble in benzene, with d_20 °C = 3.147 g/cm³.[7]

References

Haynes, William M. (2016-06-24). CRC Handbook of Chemistry and Physics 97th Edition. CRC Press. pp. 4–83. ISBN 978-1-4987-5428-6.
林平娣, 吴国庆. 无水三溴化钐和三溴化镱的制备 Archived 2022-01-01 at the Wayback Machine[J]. 化学试剂, 1991(1):13-14.
"Samarium(III) bromide anhydrous, beads, −10 mesh, 99.99% | Sigma-Aldrich". www.sigmaaldrich.com. Retrieved 21 December 2016.
Elements, American. "Samarium(III) Bromide Hexahydrate". American Elements. Retrieved 21 December 2016.
Christoph Janiak, Hans-Jürgen Meyer, Dietrich Gudat, Ralf Alsfasser (2012). Riedel Moderne Anorganische Chemie. Walter de Gruyter. ISBN 978-3-11-024901-9.{{cite book}}: CS1 maint: multiple names: authors list (link)
Wells, A. F. (1984). Structural Inorganic Chemistry (5th ed.). Oxford University Press. p. 421. ISBN 978-0-19-965763-6.
Uchenye zapiski: Serii︠a︡ khimicheskikh nauk (SM Kirov adyna Azărbai̐jan Dȯvlăt Universiteti; 1977), page 37. Retrieved 14 March 2021.

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[CRC_Handbook_of_Chemistry_and_Physics_97th_Edition-1] Haynes, William M. (2016-06-24). CRC Handbook of Chemistry and Physics 97th Edition. CRC Press. pp. 4–83. ISBN 978-1-4987-5428-6.

[Lin-2] 林平娣, 吴国庆. 无水三溴化钐和三溴化镱的制备 Archived 2022-01-01 at the Wayback Machine[J]. 化学试剂, 1991(1):13-14.

[sigma-3] "Samarium(III) bromide anhydrous, beads, −10 mesh, 99.99% | Sigma-Aldrich". www.sigmaaldrich.com. Retrieved 21 December 2016.

[Americanelements-4] Elements, American. "Samarium(III) Bromide Hexahydrate". American Elements. Retrieved 21 December 2016.

[Christoph_Janiak,_Hans-Jürgen_Meyer,_Dietrich_Gudat,_Ralf_Alsfasser-5] Christoph Janiak, Hans-Jürgen Meyer, Dietrich Gudat, Ralf Alsfasser (2012). Riedel Moderne Anorganische Chemie. Walter de Gruyter. ISBN 978-3-11-024901-9.{{cite book}}: CS1 maint: multiple names: authors list (link)

[Wells421-6] Wells, A. F. (1984). Structural Inorganic Chemistry (5th ed.). Oxford University Press. p. 421. ISBN 978-0-19-965763-6.

[7] Uchenye zapiski: Serii︠a︡ khimicheskikh nauk (SM Kirov adyna Azărbai̐jan Dȯvlăt Universiteti; 1977), page 37. Retrieved 14 March 2021.