Berkelium(III) bromide

Berkelium bromide is a bromide of berkelium, with the chemical formula BkBr3.

Berkelium(III) bromide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Bk.3BrH/h;3*1H/q+3;;;/p-3
    Key: QXVXDBUNYGKXIG-UHFFFAOYSA-K
  • [Br-].[Br-].[Br-].[Bk+3]
Properties
BkBr3
Molar mass 487 g·mol−1
Appearance yellow-green crystals[1]
Related compounds
Other anions
 Berkelium fluoride
Berkelilum chloride
Berkelium iodide
Other cations
 Curium bromide
Californium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Structure

Berkelium bromide has a PuBr3 structure at low temperature and is in the orthorhombic crystal system, with lattice parameters a = 403 pm, b = 1271 pm and c = 912 pm.[2] At high temperature, berkelium bromide has an AlCl3 structure and a monoclinic crystal system with lattice parameters a = 723 pm, b = 1253 pm, c = 683 pm and β = 110.6°.[2][3][4][5]

References
  1. A. F. Holleman, E. Wiberg, N. Wiberg: Lehrbuch der Anorganischen Chemie. 102. Auflage. Walter de Gruyter, Berlin 2007, ISBN 978-3-11-017770-1, S. 1969.
  2. Burns, John H.; Peterson, J.R.; Stevenson, J.N. (Mar 1975). "Crystallographic studies of some transuranic trihalides: 239PuCl3, 244CmBr3, 249BkBr3 and 249CfBr3". Journal of Inorganic and Nuclear Chemistry. 37 (3): 743–749. doi:10.1016/0022-1902(75)80532-X.
  3. Young, J. P.; Haire, R. G.; Peterson, J. R.; Ensor, D. D.; Fellows, R. L. (Aug 1980). "Chemical consequences of radioactive decay. 1. Study of californium-249 ingrowth into crystalline berkelium-249 tribromide: a new crystalline phase of californium tribromide". Inorganic Chemistry. 19 (8): 2209–2212. doi:10.1021/ic50210a003. ISSN 0020-1669.
  4. Cohen, D.; Fried, S.; Siegel, S.; Tani, B. (May 1968). "The preparation and crystal structure of some berkelium compounds". Inorganic and Nuclear Chemistry Letters. 4 (5): 257–260. doi:10.1016/0020-1650(68)80125-4.
  5. Peterson, J.R.; Hobart, D.E. (1984), "The Chemistry of Berkelium", Advances in Inorganic Chemistry, Elsevier, vol. 28, pp. 29–72, doi:10.1016/s0898-8838(08)60204-4, ISBN 978-0-12-023628-2, retrieved 2023-06-26

External reading
  • Hobart, David E.; Peterson, Joseph R. (2006), Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.), "Berkelium", The Chemistry of the Actinide and Transactinide Elements, Dordrecht: Springer Netherlands, pp. 1444–1498, doi:10.1007/1-4020-3598-5_10, ISBN 978-1-4020-3555-5, retrieved 2023-06-26
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