Zirconyl acetate
Zirconyl acetate is the coordination complex with the formula Zr6O4(OH)4(O2CCH3)12. It is a white solid prepared by treating zirconyl chloride with acetic acid. The compound has attracted attention as a precursor to metal-organic frameworks. The structure of the 8.5 hydrate has been determined by EXAFS. The core can be described as a Zr6 octahedron is face-capped with oxide and hydroxide ligands.[1]
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| Identifiers | |
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| ECHA InfoCard | 100.023.568 |
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CompTox Dashboard (EPA) |
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| Properties | |
| C24H40O32Zr6 | |
| Molar mass | 1387.896 g·mol−1 |
| Appearance | white solid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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References
- Hennig, Christoph; Weiss, Stephan; Kraus, Werner; Kretzschmar, Jerome; Scheinost, Andreas C. (2017). "Solution Species and Crystal Structure of Zr(IV) Acetate". Inorganic Chemistry. 56 (5): 2473–2480. doi:10.1021/acs.inorgchem.6b01624. PMID 28199091.
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