Hilkka I. Kenttämaa

Hilkka Inkeri Kenttämaa is a researcher in organic and bioorganic mass spectrometry, and the Frank Brown Endowed Distinguished Professor of Chemistry at Purdue University. She is a pioneer in distonic radical cation research and laser-induced acoustic desorption.

Hilkka Kenttämaa
Alma materUniversity of Helsinki(BS MS Phil.Lic. PhD)
AwardsFrank H. Field and Joe L. Franklin ACS Award for Outstanding Achievement in Mass Spectrometry(2015)
Scientific career
FieldsChemistry
InstitutionsPurdue University
ThesisUnimolecular Gas Phase Reactions of Some Organophosphorus Ester Ions and Effects of Stepwise Collisional Excitation (1986)

Early life and education

Kenttämaa had initially planned to study mathematics, instead of chemistry, despite both her parents being chemists.[1] She studied at Helsinki University, earning a BS in 1977, a MS in 1978, a Phil. Lic.in 1981, and a PhD in Organic Chemistry in 1986. She did post-doctoral research with R. Graham Cooks at Purdue University in 1986.[2]

Career

She began her career as a research scientist at Helsinki University, the Academy of Finland, and as a visiting research scientist at Purdue University. She joined the faculty at Purdue University in 1989, and was promoted to Full Professor in 1999.[3] Her projects include using tandem mass spectrometry to study reaction mechanisms[4][5] and fast pyrolysis process.[6] She is a pioneer in distonic radical cation research[7] and laser-induced acoustic desorption.[1][8][9]

She was elected as a member of the Finish Academy of Science in 2004.[10] She serves as a subject editor in basic mass spectrometry for Mass Spectrometry Reviews.[11]

Honors and awards

Selected publications

Below is a list of articles co-authored by Kenttämaa, with over 100 citations:

  • Vicki H. Wysocki; Hilkka I. Kenttämaa; R. Graham Cooks (1987) "Internal energy distributions of isolated ions after activation by various methods". International Journal of Mass Spectrometry and Ion Processes 75 (2): 181–208.[23]
  • Krista M. Stirk; L. K. Marjatta Kiminkinen; Hilkka I. Kenttamaa (1992) "Ion-molecule reactions of distonic radical cations". Chemical Reviews 92 (7):1649–1665.[24]
  • David S. Pinkston; Penggao Duan; Vanessa A. Gallardo; Steven C. Habicht; Xiaoli Tan; Kuangnan Qian; Murray Gray; Klaus Müllen; Hilkka I. Kenttämaa (2009) "Analysis of asphaltenes and asphaltene model compounds by laser-induced acoustic desorption/Fourier transform ion cyclotron resonance mass spectrometry". Energy Fuels 23 (11): 5564–5570.[25]
  • David Borton, II; David S. Pinkston; Matthew R. Hurt; Xiaoli Tan; Khalid Azyat; Alexander Scherer; Rik Tykwinski; Murray Gray; Kuangnan Qian; Hilkka I. Kenttämaa (2010) "Molecular structures of asphaltenes based on the dissociation reactions of their ions in mass spectrometry". Energy Fuels 24 (10): 5548–5559.[26]
  • Trenton H. Parsell; Benjamin C. Owen; Ian Klein; Tiffany M. Jarrell; Christopher L. Marcum; Laura J. Haupert; Lucas M. Amundson; Hilkka I. Kenttämaa; Fabio Ribeiro; Jeffrey T. Miller; Mahdi M. Abu-Omar  (2013) "Cleavage and hydrodeoxygenation (HDO) of C–O bonds relevant to lignin conversion using Pd/Zn synergistic catalysis". Chemical Science 4 (2): 806–813.[27]
  • Trenton Parsell; Sara Yohe; John Degenstein; Tiffany Jarrell; Ian Klein; Emre Gencer; Barron Hewetson; Matt Hurt; Jeong Im Kim; Harshavardhan Choudhari; Basudeb Saha; Richard Meilan; Nathan Mosier; Fabio Ribeiro; W. Nicholas Delgass; Clint Chapple; Hilkka I. Kenttämaa; Rakesh Agrawal; Mahdi M. Abu-Omar (2015) "A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass". Green Chemistry 17 (3): 1492–1499.[28]
  • Hao Luo; Ian M. Klein; Yuan Jiang; Hanyu Zhu; Baoyuan Liu; Hilkka I. Kenttämaa; Mahdi M. Abu-Omar (2016) "Total utilization of miscanthus biomass, lignin and carbohydrates, using earth abundant nickel catalyst". ACS Sustainable Chemistry & Engineering 4 (4): 2316–2322.[29]

Book chapter

  • Kawthar Z. Alzarieni; Hilkka I. Kenttämaa. "The distillation precipitation fractionation mass spectrometry (DPF-MS) method for molecular profiling of crude oil" in The Chemistry of Oil and Petroleum Products. Merv Fingas (Ed.). De Gruyter 2022.[30]

Patent applications
  • High power laser induced acoustic desorption probe (2007) US 7619217 B2[31]
  • Laser-induced acoustic desorption/atmospheric pressure chemical ionization of compounds(2011) US 8344319 B2[32]
  • Sample deposition chamber for laser-induced acoustic desorption (liad) foils (2012) WO 2013103417 A3[33]
  • Differentially pumped dual linear quadrupole ion trap mass spectrometer (2015) US 9496127 B2[34]
  • Multichannel Pulsed Valve Inlet System (2019) US[35]

References
  1. Thayer, Ann M. (2015). "Frank H. Field & Joe L. Franklin Award For Outstanding Achievement In Mass Spectrometry". ACS Chemical and Engineering News. Retrieved 2022-06-07.
  2. "Purdue Chemistry: Kenttämaa Labs: Hilkka I. Kenttämaa". www.chem.purdue.edu. Retrieved 2022-06-07.
  3. "Purdue University: College of Science: Chemistry professor receives distinguished honors". www.purdue.edu. Retrieved 2022-06-07.
  4. Feng, Erlu; Ma, Xin; Kenttämaa, Hilkka I. (2021-06-08). "Characterization of Protonated Substituted Ureas by Using Diagnostic Gas-Phase Ion-Molecule Reactions Followed by Collision-Activated Dissociation in Tandem Mass Spectrometry Experiments". Analytical Chemistry. 93 (22): 7851–7859. doi:10.1021/acs.analchem.1c00326. ISSN 0003-2700. PMID 34028247. S2CID 235168836.
  5. Kumar, Rashmi; Kenttämaa, Hilkka I. (2020-10-07). "Effects of Analyte Concentration on the Protonation Sites of 4-Aminobenzoic Acid upon Atmospheric Pressure Chemical Ionization As Revealed by Gas-Phase Ion–Molecule Reactions". Journal of the American Society for Mass Spectrometry. 31 (10): 2210–2217. doi:10.1021/jasms.0c00285. ISSN 1044-0305. PMID 32852952. S2CID 221359886.
  6. Yu, Zaikuan; Murria, Priya; Easton, Mckay W.; Degenstein, John C.; Zhu, Hanyu; Xu, Lan; Agrawal, Rakesh; Delgass, W. Nicholas; Ribeiro, Fabio H.; Kenttämaa, Hilkka I. (2019-10-24). "Exploring the Reaction Mechanisms of Fast Pyrolysis of Xylan Model Compounds via Tandem Mass Spectrometry and Quantum Chemical Calculations". The Journal of Physical Chemistry A. 123 (42): 9149–9157. doi:10.1021/acs.jpca.9b04438. ISSN 1089-5639. PMID 31545607. S2CID 202748635.
  7. Kiminkinen, L. K. Marjatta; Stirk, Krista G.; Kenttamaa, Hilkka I. (1992). "A remarkably stable organic radical cation: the distonic isomer of the unstable radical cation of dimethyl propyl phosphate". Journal of the American Chemical Society. 114 (6): 2027–2031. doi:10.1021/ja00032a015. ISSN 0002-7863.
  8. Jarrell, Tiffany M.; Owen, Benjamin C.; Riedeman, James S.; Prentice, Boone M.; Pulliam, Chris J.; Max, Joann; Kenttämaa, Hilkka I. (2017-06-01). "Laser-Induced Acoustic Desorption/Electron Ionization of Amino Acids and Small Peptides". Journal of the American Society for Mass Spectrometry. 28 (6): 1091–1098. doi:10.1007/s13361-017-1684-1. ISSN 1044-0305. PMID 28500583. S2CID 41709530.
  9. Ma, Xin; Zhang, Yuyang; Lei, Hao-Ran; Kenttämaa, Hilkka I. (2019-05-01). "Laser-induced acoustic desorption". MRS Bulletin. 44 (5): 372–381. doi:10.1557/mrs.2019.105. ISSN 1938-1425. S2CID 164846809.
  10. "Ulkomaiset jäsenet". Tiedeakatemia (in Finnish). Retrieved 2022-06-07.
  11. "Mass Spectrometry Reviews Editorial Board". Wiley Analytical Science Mass Spectrometry Reviews. Retrieved June 7, 2022.
  12. "ASMS News". Journal of the American Society for Mass Spectrometry. 2 (4): 350–353. 1991-08-01. doi:10.1016/1044-0305(91)80027-5. ISSN 1044-0305.
  13. "News and Views" (PDF). American Society for Mass Spectrometry. 2015. Retrieved 2022-06-07.
  14. "Research Awards". www.asms.org. Retrieved 2022-06-07.
  15. "NSF Award Search: Award # 9631701 - Oxidative Damage and Repair of Biological Macromolecules". www.nsf.gov. Retrieved 2022-06-07.
  16. "Hikka Kenttamaa presented 2009 Provost's Award for Outstanding Graduate Faculty Mentor - Purdue University Department of Chemistry". www.chem.purdue.edu. Retrieved 2022-06-07.
  17. "ACS 2015 National Award Winners". ACS Chemical & Engineering News. 2014-08-11. Retrieved 2022-06-07.
  18. "2015-16 Innovators Hall of Fame Inductees - Office of Technology Commercialization - Purdue University". www.prf.org. Retrieved 2022-06-07.
  19. "2016 Fellows | American Association for the Advancement of Science". www.aaas.org. Retrieved 2022-06-07.
  20. "Hilkka Kenttamaa". The Analytical Scientist. Retrieved 2022-06-07.
  21. "Purdue researchers part of team honored by NASA". School of Aeronautics and Astronautics - Purdue University. Retrieved 2022-06-07.
  22. Hoffpauir, Daniel (2020-11-25). "2020 NASA Engineering and Safety Center Honor Awards". NASA. Retrieved 2022-06-07.
  23. Wysocki, Vicki H.; Kenttämaa, Hilkka I.; Cooks, R.Graham (1987). "Internal energy distributions of isolated ions after activation by various methods". International Journal of Mass Spectrometry and Ion Processes. 75 (2): 181–208. doi:10.1016/0168-1176(87)83054-9.
  24. Stirk, Krista M.; Kiminkinen, L. K. Marjatta; Kenttamaa, Hilkka I. (1992). "Ion-molecule reactions of distonic radical cations". Chemical Reviews. 92 (7): 1649–1665. doi:10.1021/cr00015a008. ISSN 0009-2665.
  25. Pinkston, David S.; Duan, Penggao; Gallardo, Vanessa A.; Habicht, Steven C.; Tan, Xiaoli; Qian, Kuangnan; Gray, Murray; Müllen, Klaus; Kenttämaa, Hilkka I. (2009-11-19). "Analysis of Asphaltenes and Asphaltene Model Compounds by Laser-Induced Acoustic Desorption/Fourier Transform Ion Cyclotron Resonance Mass Spectrometry". Energy & Fuels. 23 (11): 5564–5570. doi:10.1021/ef9006005. ISSN 0887-0624.
  26. Borton, David; Pinkston, David S.; Hurt, Matthew R.; Tan, Xiaoli; Azyat, Khalid; Scherer, Alexander; Tykwinski, Rik; Gray, Murray; Qian, Kuangnan; Kenttämaa, Hilkka I. (2010-10-21). "Molecular Structures of Asphaltenes Based on the Dissociation Reactions of Their Ions in Mass Spectrometry". Energy & Fuels. 24 (10): 5548–5559. doi:10.1021/ef1007819. ISSN 0887-0624.
  27. Parsell, Trenton H.; Owen, Benjamin C.; Klein, Ian; Jarrell, Tiffany M.; Marcum, Christopher L.; Haupert, Laura J.; Amundson, Lucas M.; Kenttämaa, Hilkka I.; Ribeiro, Fabio; Miller, Jeffrey T.; Abu-Omar, Mahdi M. (2013). "Cleavage and hydrodeoxygenation (HDO) of C–O bonds relevant to lignin conversion using Pd/Zn synergistic catalysis". Chem. Sci. 4 (2): 806–813. doi:10.1039/C2SC21657D. ISSN 2041-6520.
  28. Parsell, Trenton; Yohe, Sara; Degenstein, John; Jarrell, Tiffany; Klein, Ian; Gencer, Emre; Hewetson, Barron; Hurt, Matt; Kim, Jeong Im; Choudhari, Harshavardhan; Saha, Basudeb (2015). "A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass". Green Chemistry. 17 (3): 1492–1499. doi:10.1039/C4GC01911C. ISSN 1463-9262. OSTI 1210426.
  29. Luo, Hao; Klein, Ian M.; Jiang, Yuan; Zhu, Hanyu; Liu, Baoyuan; Kenttämaa, Hilkka I.; Abu-Omar, Mahdi M. (2016-04-04). "Total Utilization of Miscanthus Biomass, Lignin and Carbohydrates, Using Earth Abundant Nickel Catalyst". ACS Sustainable Chemistry & Engineering. 4 (4): 2316–2322. doi:10.1021/acssuschemeng.5b01776. ISSN 2168-0485.
  30. Fingas, Merv, ed. (2022-05-23). The Chemistry of Oil and Petroleum Products. De Gruyter. doi:10.1515/9783110694529. ISBN 978-3-11-069452-9. S2CID 249083493.
  31. US application 7619217B2 Ryan C Shea, Hilkka I Kenttamaa, Weldon E Vaughn, Steven C Habicht, James Perez/Purdue Research Foundation: "High power laser induced acoustic desorption probe" filing date 29.05.2007
  32. US application 8344319B2 Hilkka I. Kenttamaa, II David Jesse Borton, Jinshan Gao, Zhicheng Jin, Benjamin Curtis Owen/Purdue Research Foundation: "Laser-induced acoustic desorption/atmospheric pressure chemical ionization of compounds" filing date 05.04.2011
  33. WO application 2013103417A3 David J. BORTON, Nelson R. VINUEZA BENITEZ, Lucas M. AMUNDSON, Matthew R. HURT, Hilkka I. KENTTAMAA/Purdue Research Foundation: "Sample deposition chamber for laser-induced acoustic desorption (liad) foils" filing date 10.10.2012
  34. US application 9496127B2 Benjamin C. Owen, Hilkka I. Kenttamaa/Purdue Research Foundation: "Differentially pumped dual linear quadrupole ion trap mass spectrometer" filing date 15.09.2015
  35. "Multichannel Pulsed Valve Inlet System | Purdue OTC". inventions.prf.org. Retrieved 2022-06-07.
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