Capped square antiprismatic molecular geometry

In chemistry, the capped square antiprismatic molecular geometry describes the shape of compounds where nine atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a gyroelongated square pyramid.

Capped square antiprismatic molecular geometry
Point groupC4v
Coordination number9

The gyroelongated square pyramid is a square pyramid with a square antiprism connected to the square base. In this respect, it can be seen as a "capped" square antiprism (a square antiprism with a pyramid erected on one of the square faces).

It is very similar to the tricapped trigonal prismatic molecular geometry, and there is some dispute over the specific geometry exhibited by certain molecules.

Examples
  • ReH2−
    9     is sometimes described as having a capped square antiprismatic geometry, although its geometry is most often described as tricapped trigonal prismatic.
  • [LaCl(H
    2    O)
    7    ]4+
    2    , a lanthanum(III) complex with a La–La bond.[1]

References
  1. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 917. ISBN 978-0-08-037941-8.


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