Silver tetrafluoroborate

Silver tetrafluoroborate is an inorganic compound with the chemical formula AgBF4. It is a white solid that dissolves in polar organic solvents as well as water. In its solid state, the Ag+ centers are bound to fluoride.[2]

Silver tetrafluoroborate
Names
IUPAC name
Silver tetrafluoridoborate(1–)
Other names
Borate(1-), tetrafluoro-, silver(1+)
Argentous tetrafluoroborate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.491
EC Number
  • 237-956-5
RTECS number
  • ED2875000
  • InChI=1S/Ag.BF4/c;2-1(3,4)5/q+1;-1 checkY
    Key: CCAVYRRHZLAMDJ-UHFFFAOYSA-N checkY
  • InChI=1/Ag.BF4/c;2-1(3,4)5/q+1;-1
    Key: CCAVYRRHZLAMDJ-UHFFFAOYAH
  • [Ag+].F[B-](F)(F)F
Properties
AgBF4
Molar mass 194.673 g/mol
Appearance Off-white powder
Odor almost odorless
Density 4.16 g/cm3
Melting point 71.5 °C (160.7 °F; 344.6 K) (monohydrate)
soluble
Hazards
GHS labelling:[1]
GHS05: Corrosive
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond
3
0
0
Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Preparation

Silver tetrafluoroborate is prepared by the reaction between boron trifluoride and silver oxide in the presence of benzene.

Laboratory uses

In the inorganic and organometallic chemistry laboratory, silver tetrafluoroborate, sometimes referred to "silver BF-4", is a useful reagent. In dichloromethane, silver tetrafluoroborate is a moderately strong oxidant.[3] Similar to silver hexafluorophosphate, it is commonly used to replace halide anions or ligands with the weakly coordinating tetrafluoroborate anions. The abstraction of the halide is driven by the precipitation of the appropriate silver halide.

References
  1. "Silver tetrafluoroborate". pubchem.ncbi.nlm.nih.gov. Retrieved 15 December 2021.
  2. Evgeny Goreshnik, Zoran Mazej, "X-ray single crystal structure and vibrational spectra of AgBF4" Solid State Sciences 2005, Volume 7, pp. 1225–1229. doi:10.1016/j.solidstatesciences.2005.06.007
  3. N. G. Connelly, W. E. Geiger (1996). "Chemical Redox Agents for Organometallic Chemistry". Chemical Reviews. 96 (2): 877–910. doi:10.1021/cr940053x. PMID 11848774.


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