Paul Hugh Emmett

Paul Hugh Emmett (September 22, 1900 – April 22, 1985) was an American chemist best known for his pioneering work in the field of catalysis and for his work on the Manhattan Project during World War II. He spearheaded the research to separate isotopes of uranium and to develop a corrosive uranium gas. Emmett also made significant contributions to BET Theory which explains the relationship between surface area and gas adsorption. He served on the faculty of Johns Hopkins University for 23 years throughout his scientific career.

Paul Hugh Emmett
Emmett in 1955
Born(1900-09-22)September 22, 1900
Portland, Oregon, US
DiedApril 22, 1985(1985-04-22) (aged 84)
Portland, Oregon, US
Resting placeRiver View Cemetery Portland, Oregon
Alma materUndergraduate:Oregon State University
Graduate: California Institute of Technology
Known forCatalysis, BET theory
AwardsAppointed to National Academy of Sciences
Scientific career
InstitutionsJohns Hopkins University

California Institute of Technology Mellon Institute of Industrial Research Columbia University Oregon State University

Portland State University
Doctoral advisorArthur F. Benton
Notable studentsRowland Hansford

Early life

Paul Hugh Emmett was born on September 22, 1900, in Portland, Oregon to John Hugh Emmett (1864-1943) and Lavina Hutchins (1870-1941). Emmett's father was a railroad engineer. For a year in his early childhood, Emmett's family lived in a rail car while his mother worked as a cook for the rail company. Emmett attended Washington High School where he excelled in language and mathematics classes. Among his acquaintances in high school was Linus Pauling, future two-time Nobel Prize winner. Emmett had a fear of public speaking, so he enrolled in the debate team in both high school and college to gain proficiency.[1] His first high school science classes, physics and chemistry, were taken during his senior year of high school.[2] Emmett's senior year chemistry teacher, William Green, is said to have inspired him to pursue a career in chemistry. Later in life, Emmett expressed that perhaps high schools are "simply not flexible enough for the people in the genius class."[3]

In 1918, Emmett began his studies in chemical engineering at Oregon State University. After completing his bachelor's degree in 1922, Emmett pursued his PhD in physical chemistry at the California Institute of Technology under Arthur F. Benton. At the time, the California Institute of Technology was paying PhD students nearly double what other programs were offering, making the university an enticing choice for Emmett.[4]

Career

In 1925, Emmett accepted a teaching position at Oregon State University, but only remained for a year. In 1926, he moved to Washington, D.C. to work at the US Department of Agriculture's Fixed Nitrogen Research Laboratory. For over a decade, Emmett led experiments attempting to incorporate catalysis into the synthesis of ammonia.[1] He also worked on implementing catalysis in projects ranging form the decomposition of ammonia to water-gas conversion. Emmett also served as a lecturer at George Washington University while in Washington, D.C.[5]

Emmett joined Johns Hopkins University in 1937 to establish the Department of Chemical and Gas Engineering alongside Ralph Witt, Charles Bonilla, and Lloyd Logan.[6] He was the chair of the department from 1937 to 1943. During this period, Emmett published his famous work on the Brunauer-Emmett-Teller (BET) Theory, which later earned him a Nobel Prize in Chemistry nomination in 1967.[7][8]

In 1943, Emmett left Johns Hopkins University to become a division chief on the Manhattan Project at Columbia University under the directive of Harold Urey. For 16 months, Emmett's lab focused on separating uranium isotopes and converting uranium into a corrosive gas.[7] Emmett remained on the Manhattan Project as a consultant for the Oak Ridge National Laboratory for 22 years.[3] In 1944, he relocated to the Mellon Institute of Industrial Research in Pittsburgh, PA to conduct petroleum research.

In 1955, Emmett moved back to Johns Hopkins University, albeit in a different department, as the William R. Grace Professor of Chemistry. He was active both nationally and internationally with various chemistry committees and conferences. He was elected to National Academy of Sciences in 1955. Emmett finished his career at Johns Hopkins University, retiring in 1971 with the professor emeritus distinction.

For the remainder of his life, Emmett was a visiting research professor at Portland State University, undertaking new research areas, giving seminar talks, and teaching advanced courses in catalysis.[5]

Personal life

Emmett was a close friend and classmate of Linus Pauling with whom he attended high school, college, and graduate school.

Emmett was married to Leila Jones on July 14, 1930, until her death in 1968. He had a short second marriage which ended in divorce. Pauling became brother-in-law to Emmett after he married Pauling's older sister, Pauline, in 1976. She survived him, eventually passing away in 2003 at the age of 101.[9]

Death and legacy

Emmett had Parkinson's disease and a brain tumor during the later stages of his life.[5] He died on April 22, 1985, at the age of 84.

In total, Emmett authored 164 publications, some of which are still cited to this day.[4] The Paul Hugh Emmett award was established in 1972 by the Catalysis Society of North America.[5]

Research

Doctoral work and thesis

Emmett's doctoral advisor, Arthur F. Benton, had studied under Hugh Stott Taylor at Princeton University. Emmett worked with Benton to study the role of nickel catalysts in the formation of water from hydrogen and oxygen gas.[10] Emmett's thesis was on the autocatalysis of the nickel and iron metal oxide reduction reaction with hydrogen gas.[11] In 1925 while at Caltech, Emmett and Linus Pauling published a paper together on the crystal structure of barium sulfate.[12]

Nitrogen fixation

At the Fixed Nitrogen Research Laboratory, Emmett's research goals were to study nitrogen fixation and its applications to the production of fertilizer, food, and explosives. Emmett also studied the synthesis and decomposition of ammonia over iron catalysts and gaseous adsorption during his 11 years at this lab. He used stable nitrogen isotopes to study the mechanisms of the catalytic reactions.[1]

BET theory
Main article: BET theory

In conjunction with Stephen Brunauer and Edward Teller, Emmett developed the Brunauer-Emmett-Teller Theory which forms the basis for calculating the surface area of a material given the physical gaseous adsorption that takes place across the material's surface. Their theory was published in 1938 in the Journal of the American Chemical Society and has been cited over 16,000 times.[13] The ramifications of this theory are immense in the catalysis field and this theory is still the "most frequently used method for surface area determinations of porous carbons."[8]

Manhattan Project
Main article: Manhattan Project

Emmett's lab focused on separating Uranium-235 and Uranium-238, as the first of five labs to work on the atomic bomb. They used a fluorocarbon polymeric barrier to separate the two isotopes via diffusion.[2] The lab also sought to synthesize the corrosive uranium hexafluoride gas. However, this gas corroded through the material used to make it, so a researcher in Emmett's lab came up with a material that served as the predecessor to Teflon. Later in life, Emmett expressed great pride in his work on the Manhattan project.[2][7]

Petroleum research

During his 11 years at the Mellon Institute of Industrial Research, much of Emmett's work was funded by Gulf Oil. Emmett improved on the Fischer-Tropsch process, a key process used to synthesize petroleum hydrocarbon substitutes. He used radioisotopes like Carbon-14 to study the mechanism of catalytic reactions. In the 1950s, Emmett's research transitioned toward the field of catalytic cracking in response to a concern in oil supply.[4][5]

Honors and awards

Notable publications
  • Catalysis vol 1-5 (1954 - 1957)
  • Absorption of Gases in Multimolecular Layers (1938)
  • Calculation of Thermodynamic Functions of Adsorbed Molecules from Adsorption Isotherm Measurements: Nitrogen on Graphon (1951)
  • The Catalytic Synthesis of Water Vapor in Contact with Metallic Nickel (1925)
  • The Reduction of Nickelous and Ferric Oxides by Hydrogen (1925)
  • The Crystal Structure of Barite (1925)

References
  1. Read "Biographical Memoirs: V.67" at NAP.edu. 1995. doi:10.17226/4894. ISBN 978-0-309-05238-2.
  2. Davis, Burton (September 1986). "Paul H. Emmett (1900-1985): Six Decades of Catalysis". The Journal of Physical Chemistry. 90 (20): 4701–4705. doi:10.1021/j100411a600. ISSN 0022-3654.
  3. Davis, Burtron H. (April 1978). "Interview with Paul H. Emmett". Journal of Chemical Education. 55 (4): 248. Bibcode:1978JChEd..55..248D. doi:10.1021/ed055p248. ISSN 0021-9584.
  4. "Emmett, Paul Hugh | Encyclopedia.com". www.encyclopedia.com. Retrieved 2020-03-24.
  5. "Emmett, Paul H. (Paul Hugh), 1900-1985 - Social Networks and Archival Context". snaccooperative.org. Retrieved 2020-03-24.
  6. "About". Department of Chemical & Biomolecular Engineering. Retrieved 2020-03-25.
  7. Pasquale, -Sue De (2016-01-12). "REWIND: Catalyst for Progress". JHU Engineering Magazine. Retrieved 2020-03-25.
  8. Davis, Burtron H. (January 2017), "The BET Equation – Nominated for a Nobel Prize but Not Selected", The Posthumous Nobel Prize in Chemistry. Volume 1. Correcting the Errors and Oversights of the Nobel Prize Committee, ACS Symposium Series, vol. 1262, American Chemical Society, pp. 165–206, doi:10.1021/bk-2017-1262.ch008, ISBN 978-0-8412-3251-8
  9. "Pauline Pauling (1902-2003)". PaulingBlog. 2009-07-16. Retrieved 2020-03-25.
  10. Benton, Arthur F.; Emmett, Paul H. (March 1926). "The Catalytic Synthesis of Water Vapor in Contact with Metallic Nickel1". Journal of the American Chemical Society. 48 (3): 632–640. doi:10.1021/ja01414a013. ISSN 0002-7863.
  11. Emmett, Paul Hugh (1925). I. The Reduction of Nickelous and Ferric Oxides by Hydrogen. II. The Catalytic Synthesis of Water Vapor on the Presence of Metallic Nickel (phd thesis). California Institute of Technology.
  12. Pauling, Linus; Emmett, Paul H. (1925-04-01). "The Crystal Structure of Barite". Journal of the American Chemical Society. 47 (4): 1026–1030. doi:10.1021/ja01681a016. ISSN 0002-7863.
  13. Brunauer, S., Emmett, P. H., & Teller, E. (1938). Adsorption of gases in multimolecular layers. Journal of the American chemical society, 60(2), 309-319.
  14. "Chemical Pioneer Award". American Institute of Chemists. Retrieved 30 November 2015.
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